“…There is also a small peak for calcium hydroxide detected at 3 d, which is due to its low percentage that is in a good agreement with DSC results. Figure 7 illustrates the FTIR spectra of samples S1, S2, S4 (0%, 5%, 15% anhydrite substituted sludge) at different hydration times 3, 7, 28 and 90 d. The spectra of FTIR show a broad band at 3448 cm -1 , which is attributed to a stretching vibration of water bound in the hydration products (Kocak et al, 2013). ı3 and ı2 stretching bands generated by the C-O groups in the calcite appeared at around 1434 cm -1 and 875 cm -1 (Rodríguez et al, 2010).…”