The effect of Zn(II) ion adsorption on the durability of sodium borosilicate glasses

Tait, J. C.; Jensen, C.

doi:10.1016/0022-3093(82)90132-6

Cited by 26 publications

(19 citation statements)

References 14 publications

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“…i) X-elements could be incorporated as charge compensator: some studies reported Mg and Zn integration into the gel of Ca free glasses, and proposed that they incorporate as charge compensators for AlO 4 -entities [10,26]. When Ca and Mg are both available, Ca incorporation is usually favored [40].…”

Section: Incorporation Of X-elements In the Gelmentioning

confidence: 98%

Impact of Zn, Mg, Ni and Co elements on glass alteration: Additive effects

Aréna

Godon

Rébiscoul

et al. 2016

Journal of Nuclear Materials

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Section: Incorporation Of X-elements In the Gelmentioning

confidence: 98%

Impact of Zn, Mg, Ni and Co elements on glass alteration: Additive effects

Aréna

Godon

Rébiscoul

et al. 2016

Journal of Nuclear Materials

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“…Many studies carried out on leaching of silicate glasses containing zirconium have shown a sharp slowdown in silicon dissolution rate during their alteration [33,34,35,36]. It has been shown that glasses deteriorate much more slowly in presence of zirconium and that alterated degree of glasses significantly increases at low zirconia levels [37,38]. This is due to the appearance of a fine, zirconium-rich alteration film on surface of glass which, although it does not prevent Si leaching [39], still makes it possible to slow down the corrosion of glass silicate framework or network [30].…”

Section: Leachate Chemical Characterizationmentioning

confidence: 99%

Static Leaching and Alteration Mechanisms of Zirconium Alkali Resistant Glasses Containing Heavy Metals

Mbemba¹,

Djanarthany²,

Losno³

et al. 2019

CJAST

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The aim of this study is to understand mechanisms that occur during leaching of alkali-resistant zirconium-containing glasses in acid and alkaline solutions. For this, we have developed 5 glass compositions: two alkali-resistant model glasses type CEMFIL, V1 (with zirconium and without heavy metals) and V2 (with zirconium and heavy metals), then three glasses of fly ashes V3 (without zirconium and with heavy metals), V4 (with 30 % of V3, zirconium and heavy metals) and V5 (with 60% of V3, zirconium and heavy metals). V4 and V5 are obtained using V3 as raw material and supplementing with SiO2, ZrO2 and Na2O to give them alkali-resistant properties. Glasses leaching in acidic and basic medium led to an important basification from the first times of alteration at pH = 4 when a basification decrease is observed for solutions initially at pH = 13. Normalized elementary mass losses results showed that, glass alteration is higher for low-calcium glasses (V1 and V2) and V4 and V5 glasses have the lowest elemental mass losses at pH = 4 and 13. SIMS profiles made on glass alteration films permitted to observe behaviour of H, Na, Ca, Si and Zr elements after 28 days at pH = 4 and 13 and understand the different dissolution mechanisms involved. SIMS profiles showed that a hydrated film develops on glass surface characterized by hydrogen enrichment and sodium depletion irrespective of the glass. These glasses are also characterized by a surface enrichment of zirconium (except V3 which does not contain zirconium) whatever the pH. Hydrated film thickness confirm that V1, V2 and V3 glasses are more altered than V4 and V5 glasses. These results are confirmed by ICP-AES leachate analysis.

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“…This effect has been explained by the suppression of the initial ion exchange processes. The corrosion resistance of alkali borosilicate glasses can be enhanced significantly by adsorption of certain ions from solution, such as Al 3 þ , Ca 2 þ , Mg 2 þ , or Zn 2 þ [142]. The effect may in some cases be explained by the formation of protective layers.…”

Section: G12 Effect Of Special Ions In Solutionmentioning

confidence: 99%

Corrosion of Glass

Grambow

2011

Uhlig's Corrosion Handbook

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The effect of Zn(II) ion adsorption on the durability of sodium borosilicate glasses

Cited by 26 publications

References 14 publications

Impact of Zn, Mg, Ni and Co elements on glass alteration: Additive effects

Impact of Zn, Mg, Ni and Co elements on glass alteration: Additive effects

Static Leaching and Alteration Mechanisms of Zirconium Alkali Resistant Glasses Containing Heavy Metals

Corrosion of Glass

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