“…[6][7][8][9] 252 Cf is the main product of Cf production by this method, and its alpha decay half-life is 2.645 years, so the chemical purity of 252 Cf will also be affected by its decay product 248 Cm. 10,11 Therefore, it is of great practical signicance to conduct basic chemical experiments on californium for further research and to obtain data with practical value.…”
Section: Introductionmentioning
confidence: 99%
“…The relationship between temperature and extraction equilibrium constant can be known from eqn (10), and the thermodynamic relationship of extraction distribution ratio can be obtained by deriving eqn (11).…”
We performed basic chemical studies on Cf using NTAamide extractant. The results of experiments and DFT calculations show that NTAamide has a good coordination ability to Cf/Cm and is expected to be applied to Cf/Cm separation.
“…[6][7][8][9] 252 Cf is the main product of Cf production by this method, and its alpha decay half-life is 2.645 years, so the chemical purity of 252 Cf will also be affected by its decay product 248 Cm. 10,11 Therefore, it is of great practical signicance to conduct basic chemical experiments on californium for further research and to obtain data with practical value.…”
Section: Introductionmentioning
confidence: 99%
“…The relationship between temperature and extraction equilibrium constant can be known from eqn (10), and the thermodynamic relationship of extraction distribution ratio can be obtained by deriving eqn (11).…”
We performed basic chemical studies on Cf using NTAamide extractant. The results of experiments and DFT calculations show that NTAamide has a good coordination ability to Cf/Cm and is expected to be applied to Cf/Cm separation.
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