Shenmu bituminous coal with 4% sodium acetate added was used to investigate the characteristics of
combustion and nitrogen oxide (NOx) release in a fixed bed reactor heated by a tube furnace. The composition
of the flue gas was analyzed to investigate the effects of sodium acetate on the combustion process and NOx
emission. The experiments were carried out in a partial reductive atmosphere and a strong oxidative atmosphere.
The O2 valley value in the partial reductive atmosphere was reduced by the added sodium acetate. Sodium
acetate accelerated the combustion and shortened the combustion process. The experimental results showed
that the emissions of NO, NO2, and N2O were affected by the reacting atmosphere and the combustion
temperature. In the strong oxidative atmosphere, sodium acetate resulted in a slight NOx reduction. In the
partial reductive atmosphere, sodium acetate reduced both the peak value of NO concentration and the total
NO emission significantly. An over 30% NOx reduction efficiency was achieved at 900 °C in the partial
reductive atmosphere, which decreased with the increase in temperature. Sodium acetate was decomposed
into hydrocarbon radicals and sodium hydroxide, which can both reduce NOx emissions due to their special
reactions with the nitrogen component.