Abstract:Electrochemical and corrosion behavior of AZ31B magnesium alloy have been investigated in composite solution of MgSO4–Mg(NO3)2 (0.14 mol L−1 MgSO4, 1.86 mol L−1 Mg(NO3)2) under different sodium fluoride (NaF) concentrations.
“…However, instead a potential shift in the negative direction was observed as the BL number increases. This behavior was reported with alloys containing magnesium, 25 aluminium, 26 aluminium alloys 27 and ferrous materials. 28 No significant changes were observed in the cathodic branch of the Tafel plot for 1 BL and 4 BL samples, indicating that the corrosion protection effect is based on the suppression of anodic metal dissolution resulting in a negative shift of the free corrosion potential.…”
Section: Electrochemical Analysis Of the Model Coatingssupporting
The aim of this study is to develop nanometer‐thin epoxy‐based films on aluminium alloy AA2024‐T3 as a model coating system for high resolution corrosion studies. Spin coating was used for the layer‐by‐layer (LbL) deposition of poly‐(ethylenimine) (PEI) and poly([o‐cresyl glycidyl ether]‐co‐formaldehyde) (CNER) bilayers. The film chemistry and the cross‐linking process were characterized by means of Fourier‐transform infrared spectroscopy (FTIR). Ellipsometric data confirmed the linear increase of film thickness. The potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) results indicate the improvement of the film barrier properties with increasing film thickness. Mapping of the topography and the volta potential was performed by means of scanning Kelvin probe force microscopy (SKPFM). The results indicate the presence of a homogeneous film structure, while the intermetallic phases can still be identified below the coating. The SKPFM analysis confirmed that the model films are suitable for investigation of corrosion processes at the coating/metal interface.
“…However, instead a potential shift in the negative direction was observed as the BL number increases. This behavior was reported with alloys containing magnesium, 25 aluminium, 26 aluminium alloys 27 and ferrous materials. 28 No significant changes were observed in the cathodic branch of the Tafel plot for 1 BL and 4 BL samples, indicating that the corrosion protection effect is based on the suppression of anodic metal dissolution resulting in a negative shift of the free corrosion potential.…”
Section: Electrochemical Analysis Of the Model Coatingssupporting
The aim of this study is to develop nanometer‐thin epoxy‐based films on aluminium alloy AA2024‐T3 as a model coating system for high resolution corrosion studies. Spin coating was used for the layer‐by‐layer (LbL) deposition of poly‐(ethylenimine) (PEI) and poly([o‐cresyl glycidyl ether]‐co‐formaldehyde) (CNER) bilayers. The film chemistry and the cross‐linking process were characterized by means of Fourier‐transform infrared spectroscopy (FTIR). Ellipsometric data confirmed the linear increase of film thickness. The potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) results indicate the improvement of the film barrier properties with increasing film thickness. Mapping of the topography and the volta potential was performed by means of scanning Kelvin probe force microscopy (SKPFM). The results indicate the presence of a homogeneous film structure, while the intermetallic phases can still be identified below the coating. The SKPFM analysis confirmed that the model films are suitable for investigation of corrosion processes at the coating/metal interface.
“…The conventional epoxy coating does not contain strong acceptor functional groups and is also easy to peel out from the alloy surface due to which the grain boundary of epoxy coated Mg alloy was affected which in turn is due to the intergranular corrosion, as shown in the above surface studies of epoxy coated Mg alloy surface. [46][47][48][49][50][51] However, Mg alloy coated by the Tb functionalized graphene oxide showed that the propagation of pitting corrosion stops due to the changes in the electron ow of Tb 3+ between the alloy surface and electrolyte medium. Due to this, the corrosion current decreased and corrosion potential increased.…”
“…1(d)) are located at 50.4 eV, which is a characteristic value for the Mg 2+ oxidation, as reported earlier. 37,38 The structural morphology of the ZnO/MgO/Cr 2 O 3 NFs analyzed by FESEM…”
Section: Xps Analysis Of the Zno/mgo/cr 2 O 3 Nfsmentioning
In situ fabrication of a sensitive electrochemical toluene sensor probe using wet-chemically prepared ternary ZnO/MgO/Cr2O3 nanofiber (NF)-decorated glassy carbon electrode (GCE) with Nafion adhesive was the approach of this study.
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