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8.Comparison
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8.Detected constituents in landfill leachate at six sites @om With respect to questions 1, 3, and 4, considered together, the results indicated that there were no quantifiable benefits to leachate recirculation over leachate drainage with respect to methane production, carbon conversion, or leachate quality. Overall, through the decomposition process, the fraction of total carbon converted to biogas carbon ranged from about 0.10 (higher moisture content assays) to 0.50 (lower moisture content assays). The differences in carbon conversion were attributed to high rates of carboxylic acid production (exceeding consumption) in the higher moisture content assays. Cel1ulose:lignin ratios, a measure of decomposition, decreased from 4.3 (initial refuse without soil) to minimum values below 0.05 at the end of the experiment.Leachate quality was evaluated in two ways: changes in chemical concentrations through the leachatehecycle events and overall changes in constituent loading. Loading is calculated from the product of chemical concentration and moisture content to yield the total soluble mass present in a given assay. Calculation of loads addresses simple dilution effects from increased gravimetric moisture contents through the decomposition process. Linear relationships between chloride loads and other constituent loads suggested the contribution of dilution effects to observed leachate concentrations. For the recycle assays, since these were sampled only at the time of destruction, no net changes in liquid volume or leachate chemistry were introduced due I to periodic sampling. Thus, changes in gravimetric moisture content through decomposition could be carefully observed. For recycle assays where the initial moisture: dry solids ratios had initially been 3.2 to 3.2, the final ratios were 5.6 to 9.7; for assays which had higher initial ratios of 7.0 to 7.2, the final ratios were 12.2 to 15.4. With respect to the two soils in this study (question 2 above), they were added at small quantities to simulate the effects of soil cover and must be evaluated in parallel with refuse and leachate chemistry. For example, with respect to nitrogen, as a major nutrient, the total nitrogen content of the clay soil was higher than that of the sand soil, which might be expected to improve gas production rates from a...