Production of cement and aggregate used in cement-based composites causes many environmental and energy problems. Decreasing the usage of cement and aggregate is a crucial and currently relevant challenge to provide sustainability. Inert materials can also be used instead of cement and aggregates, similar to pozzolanic materials, and they have positive effects on cement-based composites. One of the inert materials used in cement-based composites is wollastonite (calcium metasilicate-CaSiO3), which has been investigated and attracted attention of many researchers. This article presents state-of-the-art research regarding fibrous concretes produced with wollastonite, such as mortars, conventional concrete, engineered cementitious composites, geopolymer concrete, self-compacting concrete, ultra-high-performance concrete and pavement concrete. The use of synthetic wollastonite, which is a novel issue, its high aspect ratio and allowing the use of waste material are also evaluated. Studies in the literature show that the use of wollastonite in different types of concrete improves performance properties, such as mechanical/durability properties, and provides environmental–economic efficiency. It has been proven by studies that wollastonite is a material with an inert structure, and, therefore, its behavior is similar to that of a fiber in cementitious composites due to its acicular particle structure.