Axillary Web Syndrome (AWS) is a common complication in patients who have undergone an axillary lymph node biopsy or dissection for breast cancer. This work aims to explore in a preliminary way the effectiveness of a therapeutic approach with Neuromuscular Taping (NMT) for the aforementioned condition. Specifically, five patients have been treated and have undergone specific evaluation of typical AWS signs and symptoms, with a particular focus on the impact on Quality of Life (QoL) and Activities of Daily Life (ADLs). The final aim is to evaluate the efficacy of an innovative approach to AWS, allowing easy application, good tolerability, and few collateral effects.