1961
DOI: 10.1016/0013-4686(61)80026-1
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The electrode kinetics of the deposition and dissolution of iron

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Cited by 768 publications
(391 citation statements)
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“…Anodic dissolution of iron followed Tafel behavior for small overpotentials (slope 40 mV/decade) and was not flow sensitive. The pH dependence agreed well with the mechanism of Bockris, et al, 20 up to pH 4. The corrosion rate at 20°C and pH 4 was under mixed control (activation-diffusion) and was flow sensitive.…”
Section: Corrosion-vol 52 Nosupporting
confidence: 89%
See 1 more Smart Citation
“…Anodic dissolution of iron followed Tafel behavior for small overpotentials (slope 40 mV/decade) and was not flow sensitive. The pH dependence agreed well with the mechanism of Bockris, et al, 20 up to pH 4. The corrosion rate at 20°C and pH 4 was under mixed control (activation-diffusion) and was flow sensitive.…”
Section: Corrosion-vol 52 Nosupporting
confidence: 89%
“…According to Bockris, et al, 20 ␣ a = 1.5 giving b a = 40 mV at 25°C, which agreed very well with the experimental findings.…”
Section: Anodic Dissolution Of Ironsupporting
confidence: 87%
“…The mechanism of iron dissolution may be described as follows according to Heusler [57] and Bockris et al [58] :…”
Section: Rust Formation Mechanismsmentioning
confidence: 99%
“…According to the previous studies, 26 the exchange current densities on pure iron in sulfuric acid solutions at pH = 2 were between 4.0 and 7.0 © 10 ¹6 A cm ¹2 . For pH = 3, they were from 1.5 to 3.5 © 10 ¹6 A cm ¹2 .…”
Section: Exchange Current Densitymentioning
confidence: 63%