1990
DOI: 10.1016/0584-8539(90)80193-3
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The electronic spectra and excited state dipole moment of 2-fluoropyridine

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Cited by 17 publications
(22 citation statements)
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“…2 and 3 show, respectively, the absorption and corrected fluorescence excitation spectra of 2-and 3-FP vapors at 10 Torr both as measured with 0.2 nm excitation bandwidth. The measured absorption spectra agree well with those reported previously [8,9]. It is seen in Figs.…”
Section: Resultssupporting
confidence: 90%
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“…2 and 3 show, respectively, the absorption and corrected fluorescence excitation spectra of 2-and 3-FP vapors at 10 Torr both as measured with 0.2 nm excitation bandwidth. The measured absorption spectra agree well with those reported previously [8,9]. It is seen in Figs.…”
Section: Resultssupporting
confidence: 90%
“…As was mentioned, the lowest excited singlet state of 2-FP vapor is 1 (p, p * ) in nature, while that of 3-FP vapor is of the 1 (n, p * ) type [8,9]. It is inferred from the present results that the nonradiative rate from the 1 (p, p * ) state increases more rapidly as compared with that from the 1 (n, p * ) state with increasing the excitation energy.…”
Section: Resultssupporting
confidence: 37%
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“…In the spectrum of Figure 1c, many vibronic bands are observed in the higher frequency side from the band origin, and these bands correspond well with the bands observed in the absorption spectrum in the vapor phase. 7 Low-frequency bands at 87, 188, 229, and 325 cm -1 , which were assigned as hot bands in the vapor phase spectrum, 7 should be ascribed to cold bands and correspond to 87, 191, 233, and 325 cm -1 , respectively, in the jet spectrum. Vibrational frequencies usually become lower with a electronic excitation because the electron is excited from a bonding orbital to an unstable antibonding orbital.…”
Section: Resultsmentioning
confidence: 99%