Vibrational properties (band position, infrared [IR], and Raman intensities)of C'N stretching mode were studied in 65 gas phase hydrogen-bonded 1:1 complexes of HCN with OH acids and NH acids using density functional theory (DFT) calculations at the B3LYP-6-311ϩϩG(d,p) level. Furthermore, general characteristics of the hydrogen bonds and vibrational changes in acids OH/NH stretching bands were also considered. Experimentally observed blue shift of the C'N stretching band promoted by hydrogen bonding, which shortens the triple bond length, is very well reproduced and quantitatively depends on the hydrogen bond length. Both IR and Raman (C'N) band intensities are enhanced, also in good agreement with the experimental results. IR intensity increase is a direct function of the hydrogen bond energy. However, the predicted Raman intensity raise is a more complex function, depending simultaneously on characteristics of both the hydrogen bond (C'N bond length) and the H-donating acid (polarizability). With these two parameters, (C'N) Raman intensities of the complexes are explained with a mean error of Ϯ2.4%.