Phys. Chem. Chem. Phys.
 2024
DOI: 10.1039/d4cp02129k
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The elusive phenylethynyl radical and its cation: synthesis, electronic structure, and reactivity

Ginny Karir,
Enrique Mendez-Vega,
Adrian Portela-Gonzalez
et al.

Abstract: The reactive phenylethynyl radical, a key to PAHs in the ISM, was detected and spectroscopically characterized along with its singlet and triplet cations, and thermal products revealing a complex puzzle containing C8H5, C8H4, and C8H2 species.

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