The enthalpy of ethanol

Specific enthalpy increments for propan-1-ol at temperatures up to 573.2 K and 11.3 MPa

“…Their measurements cannot be fitted with adequate accuracy by the Watson (14) equation. Vine and Wormald (3) found that the Watson equation was a poor fit to the enthalpies of vaporisation of ethanol, and they suggested the equation…”

“…These agreed with steam tables to within ±0.5 per cent. The calorimeter has been used to measure enthalpy increments for methanol, (2) ethanol, (3) propanone, (4) n-hexane, (1) benzene, (5) (propanone + n-hexane), (6,7) and (propanone + benzene). (8) Enthalpy increments for propan-1-ol are now reported.…”

Extraction by Subcritical and Supercritical Water, Methanol, Ethanol and Their Mixtures

“…Water The properties of hot, subcritical water, methanol, and ethanol along the saturation line are shown in Tables 2-4, respectively [1,[3][4][5][6][7][8][9][10][11][12][13]. These properties include the vapor pressures p, the molar enthalpies of vaporization ∆ V H, the density ρ, the isobaric expansibility α P , the isothermal compressibility κ T , the internal pressure P int = Tα P /κ T − p, the isobaric molar heat capacity C p , and the static permittivity ε.…”

A flash vaporizing flow calorimeter for the measurement of enthalpy increments. Test measurements onn-hexane atT= 473.2 K andT= 510.2 K and pressures up top= 5.2 MPa

“…The results of 90 test runs on steam gave enthalpy increments in agreement with steam tables to within ± 0.5 per cent. This calorimeter was capable of operation at temperatures up to T = 700 K at pressures up to p = 15 MPa, and it has been used to measure enthalpy increments for n-hexane, (7) acetone, (8) methanol, (9) ethanol, (10) (acetone + n-hexane), (11,12) benzene, (13) and (acetone + benzene). (14) The calorimeter was operated manually, and would have been difficult to automate.…”