The entropy production rate a bridge between thermodynamics and chemical kinetics

Villar, José Nieto; Rieumont, Jacques; Mansilla, Ricardo

doi:10.31349/revmexfise.19.010212

Cited by 1 publication

(2 citation statements)

References 22 publications

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“…On the other hand, it was shown [31][32][33][34] by means of an Ansatz through a functional of the rate of entropy production of the control parameters of the dynamic system, Ω , as…”

Section: Optimization Of the Principle Of Minimum Production Of Entropymentioning

confidence: 99%

“…As an alternative method to the sensitivity analysis, we proposed the use of the rate of entropy production, as a non-extremal criterion, called the Method of Dominant Steps [34,45,46]. For this, we postulate that: those steps that exhibit a greater value of entropy production would be the fundamental ones in a reaction mechanism, for fixed values of the control parameters.…”

Section: Optimization Of the Principle Of Minimum Production Of Entropymentioning

confidence: 99%

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The Rate of Entropy Production in Biophysical-Chemical Systems

Nieto-Villar,

Mansilla

2023

Preprint

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An overview of the link between nonequilibrium thermodynamics and complexity theory is offered. It is shown how the rate of entropy production can be quantified through the spectrum of the Lyapunov exponents. It was shown how the entropy production per unit of time meets the necessary and sufficient conditions to be a Lyapunov function and constitutes per se an extremal principle. The entropy production fractal dimension conjecture was established. It is shown how the rate of entropy production as a non-extremal criterion represents an alternative way of sensitivity analysis of differential equations. Finally, an extension to biophysical-chemical systems, on the one hand, the use of the dissipation function is shown, as a thermodynamic potential out of equilibrium, in the characterization of biological phase transitions. On the other hand, it was evidenced how the rate of entropy production represents a physical quantity to evaluate the complexity and robustness of cancer.

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“…On the other hand, it was shown [31][32][33][34] by means of an Ansatz through a functional of the rate of entropy production of the control parameters of the dynamic system, Ω , as…”

Section: Optimization Of the Principle Of Minimum Production Of Entropymentioning

confidence: 99%

Section: Optimization Of the Principle Of Minimum Production Of Entropymentioning

confidence: 99%

The Rate of Entropy Production in Biophysical-Chemical Systems

Nieto-Villar,

Mansilla

2023

Preprint

View full text Add to dashboard Cite

show abstract

The entropy production rate a bridge between thermodynamics and chemical kinetics

Cited by 1 publication

References 22 publications

The Rate of Entropy Production in Biophysical-Chemical Systems

The Rate of Entropy Production in Biophysical-Chemical Systems

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