Forest degradation both past and present has become a significant research focus of many disciplines in recent decades, and it is an area in which the multidisciplinarity and long-term perspectives of archaeological endeavor has the potential to make a particularly valuable contribution. One of the past craft activities that has long been linked to significant socio-economic change and associated accelerations in forest cover reduction and environmental decline is the intensification of early iron production an industry reliant on the consumption of charcoal as fuel for much of its history. However, the impact of iron production on the transformation of woodlands is dependent on a suite of interrelated factors climatic, ecological, technological and cultural only some of which have so far been adequately scrutinised. This paper explores the theoretical context that links iron production with deforestation in academic and popular cultures, examining the role that archaeology can play in investigating this association, before reviewing recent methodological approaches that aim to interrogate the relationship between metallurgy and the environment in archaeological settings.