Copper has excellent electrical conductivity, but the disadvantages of low strength and hardness limit its application range. In this paper, Cu-XCr (X=5, 7, and 9, where 5, 7, and 9 are all mass percentages) alloys were treated as the object of study; the impacts of Cr contents on the microstructure, Vickers hardness, and conductivity of Cu-XCr alloys were investigated using an XHC-SV2 upright metallographic microscope, a digital display Vickers hardness tester, and a Sigma2008C digital metal conductivity meter; the optimal Cr content was determined by the comprehensive performance parameter Z. The research results showed that the second phase of Cu-XCr alloys contained dendritic, nearly spherical, and other shapes. The size was relatively small, and the distribution was relatively uniform; the Vickers hardness improved and the electrical conductivity declined with climbing Cr content; when X=7, the comprehensive performance parameter Z of Cu-XCr alloys reached a maximum of 6.7×105 HV2·%IACS.