2011
DOI: 10.1007/s00723-011-0263-z
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The Excited Triplet State of Azoalkanes: Electron Spin Polarization and Magnetic Field Effects During Triplet-Sensitized Photolysis of trans-Azocumene in Solution

Abstract: The triplet-sensitized photodecomposition of azocumene into nitrogen and cumyl radicals is investigated by time-resolved electron paramagnetic resonance and absorption spectroscopy. The radicals are found to be created spin polarized with a yield depending on the strength of the applied magnetic field. The phenomenon arises because in triplet azocumene, the decay into radicals competes with a fast triplet-sublevel selective intersystem crossing back to the azocumene ground state. The size of the initial spin p… Show more

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