1997
DOI: 10.1002/anie.199701001
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The First Large‐Pore Vanadosilicate Framework Containing Hexacoordinated Vanadium

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Cited by 68 publications
(71 citation statements)
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“…[15] This material, dubbed AM-6, is a structural analogue of titanium silicate ETS-10, where titanium has been fully replaced by vanadium. ETS-10 has a framework consisting of ''TiO 2 '' rods, which run in two orthogonal directions and are surrounded by tetrahedral silicate units.…”
Section: Introductionmentioning
confidence: 99%
“…[15] This material, dubbed AM-6, is a structural analogue of titanium silicate ETS-10, where titanium has been fully replaced by vanadium. ETS-10 has a framework consisting of ''TiO 2 '' rods, which run in two orthogonal directions and are surrounded by tetrahedral silicate units.…”
Section: Introductionmentioning
confidence: 99%
“…To the best of our knowledge, only one paper was reported on the synthesis of vanadosilicate AM-6 membranes, where a-alumina substrates were used as support [22]. In the current study, the ETS-10 core/AM-6 shell methodology was applied in the original formation of AM-6 crystals in powder form by using ETS-10 as seeds [10,16,17]. In that way, it was aimed to investigate the formation of AM-6 thin films on ITO coated glass substrates using ETS-10 as seeds for the first time, focusing on the quality of the quantum wires and the orientation of the crystallites in those films.…”
Section: Introductionmentioning
confidence: 99%
“…Furthermore, AM-6 has novel magnetic and electric properties attributed to the valence state of vanadium in VO 3 2-quantum wire which could be easily manipulated by altering the oxidation state of vanadium [14]. Rocha et al [16] synthesized vanadosilicate AM-6 for the first time by adding ETS-10 as seed crystals into the growth solution with a molar composition of Na 2 O:0.23K 2 O:0.97SiO 2 :0.10V 2 O 5 :30H 2 O, which are named as ETS-10 core/AM-6 shell crystals. Then, Sacco, Jr. et al reported the first time synthesis of seedless vanadosilicate AM-6 crystals by using structure directing agent (SDA) with molar composition of 4.5Na 2 Yoon et al [17] synthesized seedless and template free AM-6 crystals for the first time in comparison with ETS-10 core/AM-6 shell crystals made by Rocha et al [16] and ETS-10-free AM-6 crystals containing tetramethylammonium ion (TMA ? )…”
Section: Introductionmentioning
confidence: 99%
“…5 In the absence of Ti, vanadosilicate AM-6 is obtained, which is isostructural to ETS-10. AM-6 is a microporous material composed of octahedral VO 6 and tetrahedral SiO 4 units. 6 The optical properties of AM-6 are the result of the one-dimensional -V-O-V-wires embedded into the insulating SiO 2 matrix.…”
mentioning
confidence: 99%
“…S1, ESIw). 6 The optical properties of AM-6 materials with different F/V molar ratios were characterized by UV-Vis absorption spectroscopy (Fig. 1).…”
mentioning
confidence: 99%