The excitation functions of the (γ, n) and (γ, γ′) reactions leading to the formation of the 239Pu, 241Pu, 240Am, 242Am and 243Am spontaneously fissioning isomers have been measured. The experiments have been carried out using a 17‐orbit microtron. A spark counter with pulsed feeding served as a fission fragment detector. From the excitation functions measured, the parameters of a two‐humped fission barrier have been obtained and compared with other experimental results and theoretical calculations.