2007
DOI: 10.1051/0004-6361:20078138
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The fractional ionization in dark molecular clouds

Abstract: Aims. We have studied the mechanisms which govern the degree of ionization of the gas in molecular clouds and prestellar cores, with a view to interpreting the relative abundances of the carbon-chain species C n H and their negative ions, C n H − . Methods. We followed the chemical evolution of a medium comprising gas and dust as it evolves towards its steady-state composition. Various assumptions were made concerning the grain size-distribution and the fraction of very small grains (in practice, PAH), as well… Show more

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Cited by 32 publications
(51 citation statements)
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“…Hence, lower ionization fractions (and a much weaker dependence on the assumed metal elemental abundance) are predicted by the model with PAHs. These results agrees with theoretical predictions for UV shielded gas (Lepp & Dalgarno 1988;Flower et al 2007;Wakelam & Herbst 2008).…”
Section: The Ionization Fraction Gradientsupporting
confidence: 90%
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“…Hence, lower ionization fractions (and a much weaker dependence on the assumed metal elemental abundance) are predicted by the model with PAHs. These results agrees with theoretical predictions for UV shielded gas (Lepp & Dalgarno 1988;Flower et al 2007;Wakelam & Herbst 2008).…”
Section: The Ionization Fraction Gradientsupporting
confidence: 90%
“…In particular, we take into account PAHgas processes such as neutralization reactions of atomic and molecular cations on PAH − , PAH electron attachment and photodetachment of PAH − and PAH by UV photons. Such processes can play a significant role in the ionization balance of dense molecular clouds (e.g., Lepp & Dalgarno 1988;Bakes & Tielens 1998;Flower et al 2007, Wakelam & Herbst 2008Wolfire et al 2008). We have not included larger grains in the network in order to isolate the role of PAHs in the gasphase chemistry.…”
Section: Chemical Network and Elemental Abundancesmentioning
confidence: 99%
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“…The electron abundance obtained assuming an o/p-H 2 of 1.0 × 10 −4 is probably an upper limit. This o/p ratio corresponds to a steady state of highly depleted dense gas with high abundances of H + and H + 3 capable of efficient proton exchange with H 2 (Flower et al 2007). Their replacement by other ions in less extreme situations can sustain higher o/p-H 2 ratios.…”
Section: Ionization Degree and Cosmic-ray Ionization Ratementioning
confidence: 99%
“…We adopt the dissociation factors p M calculated by Gredel et al (1989) for various species, leading to a rate per unit volume of (Flower et al 2007), where we adopt a grain albedo ω = 0.5. For CO, we adopt the highabundance, high-temperature limit of p CO = 28 for ω = 0.5 (Gredel et al 1987).…”
Section: X-ray Induced Dissociationmentioning
confidence: 99%