PRELIMINARY work on the search for substitutes for sulphur and the sulphur-containing sprays for the control of powdery mildews (Erysiphaceae) is described in Part VIII of this series (10). To the reasons there given for this investigation may be added the undesirability of applying sulphur as a fungicide to fruit or vegetables intended for canning. The materials examined in the experiments there described were chosen on account of their suitability as solvents for contact insecticides such as nicotine, pyrethrum extract or rotenone, and they were confined to oils derived from natural sources, e.g. tar and petroleum oils or glyceride oils. At the same time, spray trials were carried out using manufactured solvents of which a large range are now commercially available at prices which do not prohibit their use as spray materials. These products have the great advantage over such solvents as the tar and petroleum oils that, in many cases, their standardisation by chemical analysis is simple. This work has been continued as biological material became available and, although a rigid systematic investigation was not adhered to, it is possible to classify, on chemical lines, the materials tested under the following heads: (1) Hydrocarbons, (2) Hydroxyl-derivatives, (3) Esters.For preliminary work, ordinary commercial samples of these materials were used, and only when interesting results had been obtained with this grade were they purified or otherwise subjected to analytical control. Particulars of the preparation of the sprays are given below under the separate headings, but in all cases where emulsification or the addition of a spreader was found necessary the same material was used, namely, 0-25 per cent. Agral I, a proprietary spreader of which the sulphonates of cyclic hydrocarbons containing aliphatic side-chains are declared to be the active ingredients. In other cases the emulsifier or spreader used was a dilute soap solution prepared by the addition of oleic acid (to give 0-10 per cent.) to 0-03 per cent, sodium hydroxide.Journ. Agric. Sci. xxvi 30