The Gaussian G4 enthalpy of formation of propargylamine and propargyloxy derivatives of triazido-s-triazine

Topochemical polymerization in microparticles of crystalline triazine-based monomers: Study by conventional and ultra-fast chip calorimetry

“…The studied triazine-based compounds are soluble in polar organic solvents such as DMSO and DMF; they have a high enthalpy of formation and contain mutually reactive azide and alkyne end groups that allow synthesizing new energetic materials [30]. The reactions of 1,3-dipolar cycloaddition (1,3-DCA) of azides to unsaturated alkynes are applicable for the synthesis of nitrogen-containing energetic and bioactive materials with good selectivity and high yield [16].…”

“…They can also be used to obtain hyperbranched polymers (cf. Scheme S1) [1,30] in solutions, the kinetics of which was also specifically addressed [31].…”

Energetic Polymer Possessing Furazan, 1,2,3-Triazole, and Nitramine Subunits

“…Using combustion calorimetry, it was found that diazide 7 and dipropargyl ether 9 have enthalpy of formation +781.6 and 43.5 kJ/mol [54], respectively. Previously, only calculated values of the enthalpy of formation for any propargyl ethers bearing explosophoric groups were published [35,55].…”