Dokhan volcanics suite which is undisturbed and geographically connected to immature clastic deposits from the Hammamat molasse type sediments. The leucogranite intrusions have invaded these volcanics whereas relatively more deformed lithologies are represented by a syn-tectonic volcaniclastic metasediments association and granitic rocks. The Dokhan volcanics consists of basic, intermediate, and acidic. The basic and intermediate Dokhan volcanics are represented by andesites to basalts, which less common, while the acidic Dokhan volcanics is represented by rhyodacites, which considered the main rock unit encountered in the studied area. The geochemical values reveal that broad trends of decreasing concentrations of compatible elements with MgO, Fe2O3, FeO, MnO, CaO, Co, Sr, and Zn as well as increasing amounts of incompatible elements (Al2O3 and Na2O) with increasing SiO2 content. These geochemical characteristics are shared by Dokhan volcanics and associated Hammamat clastic sediments from Sinai and the Eastern Desert (ED) of Egypt. The geochemical behavior of Wadi Kid Dokhan volcanics are characterized by orogenic arc-type and anorogenic within-plate tectonic environments. The magma types of Dokhan volcanics are tend to be metaluminous to peraluminous, medium to high-K calc- alkaline affinities. Meanwhile, the basaltic rocks are of tholeiitic origin. The lava flow of the medium to high-K calc-alkaline post-collisional Dokhan volcanics shows a tectonomagmatic transition between the calc-alkaline arc-related magmatism and the alkaline anorogenic magmatism. The Dokhan volcanics in Sinai that were the focus of the inquiry exhibit a broad evolving compositional range (rhyolite-basalt). A typical rhyolitic composition with an average silica concentration (72.45–74.88%), an average andesitic content (58.25–59.8%), and an average basaltic content (48.83%) is also present in the Dokhan volcanics from the Eastern Desert.