The Gross Mechanism of the Victor Meyer and Hartmann Reaction<sup>1</sup>

Bothner‐By, Aksel A.; Vaughan, C. Wheaton

doi:10.1021/ja01137a048

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Brc6h4 N31

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2020

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“…In an interesting study of the displacement reaction the iodoxy group, but not the nitro group, in p-nitroiodoxybenzene was replaced by the azido group (398,399). In an explanation for this observation it was pointed out that the transition state with the lower energy does not involve a carbon-iodine double bond (49).…”

Section: Brc6h4 N3mentioning

confidence: 99%

Alkyl and Aryl Azides.

Boyer¹,

Canter²

1954

Chem. Rev.

217

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Section: Brc6h4 N3mentioning

confidence: 99%

Alkyl and Aryl Azides.

Boyer¹,

Canter²

1954

Chem. Rev.

217

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Meyer‐Hartmann Reaction

2010

Comprehensive Organic Name Reactions and Reagents

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The formation of diaryliodonium salt from the reaction between iodosobenzene (PhIO) and iodoxybenzene (PhIO 2 ) in the presence of silver (I) oxide is generally referred to as the Meyer–Hartmann reaction. The study finds that it is the iodine atom in iodosobenzene that enters into the diphenyliodonium ion, whereas the iodine atom in iodoxybenzene is oxidized to iodate. All the mechanistic features of the reaction have been proposed. This reaction has been modified by the replacement of Ag 2 O with sodium hydroxide. The diaryliodonium salt has wide application in industry.

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Victor Meyer Reaction

2010

Comprehensive Organic Name Reactions and Reagents

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The formation of a nitroalkane from the reaction between an alkyl halide and silver nitrite is known as the Victor Meyer reaction. All the mechanistic features and reaction's conditions have been discussed. The study finds that the ratio of nitroalkane and alkylnitrite varies, depending on the nature of alkyl halide and metal nitrite. This reaction is still the most convenient method for the preparation of the homologues of primary nitroalkanes higher than 1‐nitropropane. In some cases, alcohol and carbonyl compounds are also found in the reaction mixtures. This reaction has also been modified to make pure nitroalkane.

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The Gross Mechanism of the Victor Meyer and Hartmann Reaction¹

Cited by 4 publications

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Alkyl and Aryl Azides.

Alkyl and Aryl Azides.

Meyer‐Hartmann Reaction

Victor Meyer Reaction

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The Gross Mechanism of the Victor Meyer and Hartmann Reaction1

Cited by 4 publications

References 0 publications

Alkyl and Aryl Azides.

Alkyl and Aryl Azides.

Meyer‐Hartmann Reaction

Victor Meyer Reaction

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The Gross Mechanism of the Victor Meyer and Hartmann Reaction¹