1998
DOI: 10.1016/s0039-6028(97)00816-9
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The growth of magnesium chloride monolayer and multilayer structures on different transition metal (Pt, Pd, Rh) single crystals with varied orientations

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Cited by 39 publications
(48 citation statements)
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“…A similar method to that employed in the growth of NaCl thin films was utilized in the growth and ordering of LiF on Pt(111) [8]. LiF was successfully ordered by exposing the substrate, held at an elevated temperature (523 K) , to the LiF vapor emitted from a Knudsen cell operating at 890 K for 15 minutes.…”
Section: Growth Ordering and Desorption Of Lif Films On Pt(111)mentioning
confidence: 99%
See 1 more Smart Citation
“…A similar method to that employed in the growth of NaCl thin films was utilized in the growth and ordering of LiF on Pt(111) [8]. LiF was successfully ordered by exposing the substrate, held at an elevated temperature (523 K) , to the LiF vapor emitted from a Knudsen cell operating at 890 K for 15 minutes.…”
Section: Growth Ordering and Desorption Of Lif Films On Pt(111)mentioning
confidence: 99%
“…This method has been applied successfully in the surface structural investigations of other large band gap materials [5][6][7][8]. More specifically, it was used in the surface structure determination of NaCl(100), whose LEED determined structure is analogous to the LiF(100) surface structure [7], see Table 2.…”
Section: Introductionmentioning
confidence: 99%
“…7 displays the mesitylene TPD results for a well characterized MgCl 2 support film produced by thermal evaporation of MgCl 2 on Au (20). From structural information on the MgCl 2 film (12)(13)(14), the Ϸ200-K desorption site is attributed to the (001) basal plane structure where the chloride ions at the outermost layer are close-packed and the metal ions under the chloride layer are coordinated to six chloride ions. The high-temperature desorption peak can be attributed to the nonbasal planes or defects in the ionic lattice of the basal plane where the surface chloride ions are not close-packed and the metal ions beneath the chloride layer are undercoordinated.…”
Section: Resultsmentioning
confidence: 99%
“…For these compounds, the thermodynamically most stable surface is the (001) basal plane of the rhombohedral crystal structure (9,11). This surface is terminated with a close-packed chloride layer and the metal ion is shielded beneath this chloride layer (12)(13)(14). Because of this structure, the (001) surface has a very low reactivity and is difficult to activate for polymerization (15,16).…”
Section: Strategy For Preparation Of Single-site Heterogeneous Zieglementioning
confidence: 99%
“…20 However, one could interpret the mesitylene TPD data using the crystallographic data, 41 surface structure, 39 surface compositions, 9,10 the shape of microcrystals 42,43 and thermodynamics 44,45 of the titanium chloride and magnesium chloride films or crystals obtained by other techniques. X-ray diffraction (XRD) found that these halide crystals have a layered structure, each layer consisting of two monoatomic layers of chlorine ions octahedrally coordinated to intercalating metal ions.…”
Section: The Ticl Y Multilayer Film As a Model System For The Ticl 3 mentioning
confidence: 99%