The High-Resolution FTIR Spectrum of the ν1 Band of DOBr

The high-resolution FTIR spectrum of the ν6 band of C2H3D

“…This method was previously used to obtain the l a /l b ratio of the hybrid m 1 band of DOBr [15]. The process of line-intensity simulation begins with the calculation of line frequencies and line intensities using a program used previously [15] given the ground-state and the upper-state (m 6 = 1) constants which were obtained earlier in the analysis. The line-intensity values were calculated based on the type and magnitude of the transition moments.…”

High resolution spectroscopy of DOBr and molecular properties of hypobromous acid

“…[5] and were calibrated using D 2 O positions calculated from Toth's energy levels [8]. Because of the poor signal to noise ratio and the fact that all of the available calibration features were between 880 and 930 cm À1 , an additional uncertainty of approximately 0:0006 cm À1 should be added to the tabulated m 2 band origin uncertainties.…”

“…The conditions for the earlier infrared and microwave experiments have been described in the previously cited works [2,5].…”

“…Since the first observation of HOBr and DOBr rotational and infrared spectra by Koga et al [1] several high resolution studies have appeared [2][3][4][5][6][7]. These, as well as numerous reports of the optical spectrum, reaction kinetics, and ab initio studies have been undertaken as a part of a larger program to characterize reactive halogen containing molecules which may participate in the catalytic destruction of atmospheric ozone.…”