The History and Prospective of the AOPs for Environmental Applications in Colombia**

Mueses, Miguel Ángel; Castillo-Castellón, Jullieth V.; Colina–Márquez, José; Machuca-Martínez, Fiderman

doi:10.1002/slct.202103326

Cited by 1 publication

(1 citation statement)

References 95 publications

(172 reference statements)

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“…[1] In particular, methylene blue (MB) represents one of the most typical cationic dyes, which receives increasing attention due to its widespread applications and frequent discharge into various water bodies. [2] Many technologies have been employed to degrade/recycle/remove it, including physical adsorption, [3] microbial degradation, [4] chemical oxidation, [5] catalytic oxidation [6] and advanced oxidation process (AOP). [7] Particularly, the peroxymonosulfate (PMS) assisted Fenton-like process is one of the AOPs based on active species such as 1 O 2 , * OH, and SO 4 À * etc.…”

Section: Introductionmentioning

confidence: 99%

Preparation of Cobalt and Nitrogen‐Doped Porous Carbon Composite Catalysts From ZIF‐9 and Their Outstanding Fenton‐like Catalytic Properties Towards Methylene Blue

Liu

et al. 2023

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To activate peroxymonosulfate (PMS) and degrade methylene blue (MB), cobalt and nitrogen‐doped porous carbon composite catalysts were prepared through pyrolysing zeolitic imidazolate framework ZIF‐9 and dicyandiamide (DCDA) at 700–900 °C with various mass ratios. Powder X‐ray diffraction, scanning electron microscopy, transmission electron microscopy, and Brunauer‐Emmett‐Teller results showed that Co, porous carbon and carbon nanotubes (CNTs) co‐existed in the catalyst prepared at 800 °C with a ZIF‐9/DCDA ratio of 1 : 3. Thermogravimetric analysis suggested that CNT@ZIF‐800 had a higher ratio of graphitic to turbostratic carbon than CNT@ZIF‐700. It had degraded 94.8 % MB within 30 min, which was about 1.9 times faster than its counterpart C‐ZIF‐800. It also showed faster degradation rates towards Congo red (98.5 %, 5 min) and slower rates towards rhodamine B (90.7 %, 30 min) than MB. Furthermore, XPS revealed that it had 14.5 % more Co−Nx/pyridinic‐N active sites than C‐ZIF‐800. EPR suggested that 1O2 might be the primary catalytic species whereas the SO4−⋅ and ⋅OH the secondary ones. The formation mechanism of such active species might be originated from the synergistic activation of PMS by CNTs, Co−Nx/pyridinic‐N and abundant Co sites in the CNT@ZIF‐800. This work not only provided efficient Fenton‐like catalysts for MB degradation, but also clarified the catalytic mechanism.

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Section: Introductionmentioning

confidence: 99%

Preparation of Cobalt and Nitrogen‐Doped Porous Carbon Composite Catalysts From ZIF‐9 and Their Outstanding Fenton‐like Catalytic Properties Towards Methylene Blue

Liu

et al. 2023

ChemistrySelect

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The History and Prospective of the AOPs for Environmental Applications in Colombia**

Abstract: ALL (advanced AND oxidation AND processes))) AND ((ultrasound) OR (sonochemical) OR ( sonochemistry)) AND LIMIT-TO (AFFILCOUNTRY, "Colombia").

Cited by 1 publication

References 95 publications

Preparation of Cobalt and Nitrogen‐Doped Porous Carbon Composite Catalysts From ZIF‐9 and Their Outstanding Fenton‐like Catalytic Properties Towards Methylene Blue

Preparation of Cobalt and Nitrogen‐Doped Porous Carbon Composite Catalysts From ZIF‐9 and Their Outstanding Fenton‐like Catalytic Properties Towards Methylene Blue

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