The hydration of tricalcium silicate

Taylor, H. F. W.; Barret, P.; Brown, Paul; Double, D. D.; Frohnsdorff, Geoffrey; Johansen, V.; Ménétrier-Sorrentino, D.; Odler, Ivan; Parrott, Leslie; Pommersheim, James M.; Regourd, M.; Young, J. F.

doi:10.1007/bf02473986

Cited by 82 publications

(41 citation statements)

References 31 publications

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“…However, the sonicated OPC has lower ion concentrations for the first two hours of hydration than the as-delivered OPC, and larger concentrations thereafter. The maximum concentration of Ca 2+ for the sonicated OPC was substantially higher than that reported in the literature, while the final value for the as-delivered OPC was less than would typically be expected 30,31 .…”

Section: Figurecontrasting

confidence: 56%

Growth of Cement Hydration Products on Single‐Walled Carbon Nanotubes

Makar

Chan

2009

Journal of the American Ceramic Society

321

112

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/npsi/ctrl?lang=en http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/ctrl?lang=fr Access and use of this website and the material on it are subject to the Terms and Conditions set forth at http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/jsp/nparc_cp.jsp?lang=en NRC Publications Archive Archives des publications du CNRCThis publication could be one of several versions: author's original, accepted manuscript or the publisher's version. / La version de cette publication peut être l'une des suivantes : la version prépublication de l'auteur, la version acceptée du manuscrit ou la version de l'éditeur. For the publisher's version, please access the DOI link below./ Pour consulter la version de l'éditeur, utilisez le lien DOI ci-dessous.http://dx.doi.org/10.1111/j. 1551-2916.2009.03055.x Journal of the American Ceramic Society, 92, 6, pp. 1303Society, 92, 6, pp. -1310Society, 92, 6, pp. , 2009 Growth of cement hydration products on single walled carbon nanotubes Makar, J. M.; Chan, G. W. The material in this document is covered by the provisions of the Copyright Act, by Canadian laws, policies, regulations and international agreements. Such provisions serve to identify the information source and, in specific instances, to prohibit reproduction of materials without written permission. For more information visit http://laws.justice.gc.ca/en/showtdm/cs/C-42Les renseignements dans ce document sont protégés par la Loi sur le droit d'auteur, par les lois, les politiques et les règlements du Canada et des accords internationaux. Ces dispositions permettent d'identifier la source de l'information et, dans certains cas, d'interdire la copie de documents sans permission écrite. Pour obtenir de plus amples renseignements : http://lois.justice.gc.ca/fr/showtdm/cs/C-42 Growth of Cement Hydration Products on Single Walled Carbon Nanotubes AbstractSingle walled carbon nanotubes (SWCNT) were distributed on the surface of ordinary Portland cement (OPC) grains. The OPC/SWCNT composite was then hydrated at a 0.5 w/c ratio. The effects of the SWCNT on the early hydration process were studied using isothermal conduction calorimetry, high resolution scanning electron microscopy and thermogravimetric analysis. The observed behaviour of the composite samples was compared to both OPC sonicated without SWCNT and previously published data on as-delivered OPC. The SWCNT were found to accelerate the hydration reaction of the C 3 S in the OPC. The morphology of both the initial C 3 A and the C 3 S hydration products were found to be affected by the presence of the SWCNT. In particular, the nanotubes appeared to act as nucleating sites for the hydration products, with the nanotubes becoming rapidly coated with C-S-H. The resulting structures remained on the surface of the cement grains while those in the sonicated and as-delivered OPC samples grew out from the grain surfaces to form typical C-S-H clusters. Classical evidence of reinforcing behaviour, in the form of fiber pullout of the SWCNT bundles, was observed by 24 hours of hydration.

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Section: Figurecontrasting

confidence: 56%

Growth of Cement Hydration Products on Single‐Walled Carbon Nanotubes

Makar

Chan

2009

Journal of the American Ceramic Society

321

112

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“…Of these authors, Pratt and Ghose [24] and Taylor et al [28] presented no experimental results to support this view. Scrivener and Pratt [29] studied a mixture of monomineralic grains of C 3 S and C 3 A (plus hemihydrate) and found close contact between the C 3 S grains and product at 1 day.…”

Section: Hadley Grains In C 3 S and Alite Pastesmentioning

confidence: 81%

“…It has been stated that hollow shells or Hadley grains, as they also have been named after the man who first discovered them (David W Hadley [21]), seem not to form in C 3 S paste [24,28,29]. Of these authors, Pratt and Ghose [24] and Taylor et al [28] presented no experimental results to support this view.…”

Section: Hadley Grains In C 3 S and Alite Pastesmentioning

confidence: 94%

Revisiting the microstructure of hydrated tricalcium silicate––a comparison to Portland cement

Kjellsen

Justnes

2004

Cement and Concrete Composites

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“…According to Camilleri et al, white ProRoot MTA is composed primarily of tricalcium silicate and bismuth oxide whereas, gray ProRoot MTA contains tricalcium silicate, dicalcium silicate and bismuth oxide 5) . Tricalcium silicate is the most important mineral phase of PC and is responsible for the formation of calcium silicate hydrate and calcium hydroxide during the setting reaction 26) as,…”

Section: Discussionmentioning

confidence: 99%

Chemical and morphological characteristics of mineral trioxide aggregate and Portland cements

et al. 2016

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The purpose of this study was to investigate the chemical composition and particle morphology of white mineral trioxide aggregate (WMTA) and two white Portland cements (CEM 1 and CEM 2). Compositional analysis was performed by energy dispersive X-ray spectroscopy, X-ray fluorescence spectrometry and X-ray diffraction whereas, morphological characteristics were analyzed by scanning electron microscope and Laser scattering particle size distribution analyzer. The elemental composition of WMTA, CEM 1 and CEM 2 were similar except for the presence of higher amounts of bismuth in WMTA. Calcium oxide and silicon oxide constitute the major portion of the three materials whereas, tricalcium silicate was detected as the major mineral phase. The particle size distribution and morphology of WMTA was finer compared to CEM 1 and CEM 2. The three tested materials had relatively similar chemical composition and irregular particle morphologies.

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The hydration of tricalcium silicate

Cited by 82 publications

References 31 publications

Growth of Cement Hydration Products on Single‐Walled Carbon Nanotubes

Growth of Cement Hydration Products on Single‐Walled Carbon Nanotubes

Revisiting the microstructure of hydrated tricalcium silicate––a comparison to Portland cement

Chemical and morphological characteristics of mineral trioxide aggregate and Portland cements

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