Dual fluidized bed (DFB) reactor systems are widely used in gas–solid two-phase flow applications, whose gas–solid flow characteristics have a significant effect on the performance of many kinds of technologies. A numerical simulation model was established on the basis of a large-scale DFB reactor with a maximum height of 21.6 m, and numerical simulations focused on gas–solid flow characteristics were carried out. The effects of the superficial gas velocity of both beds and the static bed height and particle size on the distribution of the pressure and solid suspension density and the solid circulation rate were studied. The simulation results were in good agreement with the experimental data. With the strong support of the experimental data, the gas–solid flow characteristics of large-scale DFB reactors were innovatively evaluated in this numerical simulation study, which effectively makes up for the shortcomings of the current research. The results showed that the superficial gas velocity of both beds and the static bed height have different degrees of influence on the gas–solid flow characteristics. Specifically, for 282 μm particles, when the superficial gas velocity of both beds and the static bed height were 4.5 m/s, 2.5 m/s, and 0.65 m, respectively, under typical working conditions, the bottom pressure of the two furnaces was 3412.42 Pa and 2812.86 Pa, respectively, and the solid suspension density was 409.44 kg/m3 and 427.89 kg/m3, respectively. Based on the simulation results, the empirical formulas of the solid circulation rate were fitted according to different particle sizes. Under similar conditions, the solid circulation rates of particles with a particle size of 100 μm, 282 μm, 641 μm, and 1000 μm were 2.84–13.28, 0.73–4.91, 0.024–0.216, and 0.0026–0.0095 kg/(m2s), respectively. It can be found that the influence of the particle size on the solid circulation rate is the most significant among all parameters.