The Hydrogenolysis of Dicyclopropylmethane on Nickel Catalysts

Newham, J.; Burwell, Robert L.

doi:10.1021/j100814a015

Search citation statements

Order By: Relevance

Paper Sections

Select...

Isotopic Exchange Between Alkanes and Deuterium1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1969

1984

Publication Types

Select...

Article6

Relationship

Self Cite1

Independent5

Authors

Journals

Cited by 9 publications

(1 citation statement)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…However, if one starts with cyclopropane, a molecule of much higher free energy, 1,3-diadsorbed alkane is a very probable intermediate in the hydrogenolysis to propane. 14 1,4-Diadsorbed butane is a probable intermediate in the much slower hydrogenolysis of cyclobutane.9 The major product of exchange of norbornane contains a pair of eclipsed deuterium atoms as shown in D. Thus, 1,2diadsorbed alkanes readily form in eclipsed conformations. Staggered conformations are not favored.…”

Section: Isotopic Exchange Between Alkanes and Deuteriummentioning

confidence: 96%