Equilibrium states for geodesic flows over closed rank 1 manifolds were studied recently in Burns, Climenhaga, Fisher, and Thompson [Geom. Funct. Anal. 28 (2018), no. 5, 1209–1259]. For sufficiently regular potentials, it was shown that if the singular set does not carry full pressure, then the equilibrium state is unique. The main result of this paper is that these equilibrium states have the Kolmogorov property. In particular, these measures are mixing of all orders and have positive entropy. For the Bowen‐Margulis measure, we go further and obtain the Bernoulli property from the Kolmogorov property using classic arguments from Ornstein theory. Our argument for the Kolmogorov property is based on an idea due to Ledrappier. We prove uniqueness of equilibrium states on the product of the system with itself. To carry this out, we develop techniques for uniqueness of equilibrium states which apply in the presence of the 2‐dimensional center direction which appears for a product of flows. This is a key technical challenge of this paper.