Although the significance of sustainable supply chain finance (SSCF) has been recognized, our knowledge of its antecedents remains limited. Drawing upon organizational information processing theory (OIPT), our research explores how blockchain technology adoption influences SSCF via supply chain visibility, and the moderating role of supply chain ethical leadership. We examine the proposed relationships employing survey data from 317 manufacturers in China. The findings indicate that blockchain technology adoption positively affects SSCF. Supply visibility and demand visibility partially mediate the influence of blockchain technology adoption on SSCF. Furthermore, supply chain ethical leadership undermines the positive influence of blockchain technology adoption on demand visibility. This research enriches our understanding of the antecedents affecting SSCF by offering insights from the perspective of OIPT.