Abstract. The diurnal atmospheric boundary layer evolution of the 222 Rn decaying family is studied using a state-of-theart large-eddy simulation model. In particular, a diurnal cycle observed during the Wangara experiment is successfully simulated together with the effect of diurnal varying turbulent characteristics on radioactive compounds initially in a secular equilibrium. This study allows us to clearly analyze and identify the boundary layer processes driving the behaviour of 222 Rn and its progeny concentrations. An activity disequilibrium is observed in the nocturnal boundary layer due to the proximity of the radon source and the trapping of fresh 222 Rn close to the surface induced by the weak vertical transport. During the morning transition, the secular equilibrium is fast restored by the vigorous turbulent mixing. The evolution of 222 Rn and its progeny concentrations in the unsteady growing convective boundary layer depends on the strength of entrainment events.