Coordinating and controlling carbon and atmospheric pollutant emissions in industrial cities poses challenges, making it difficult to formulate effective environmental governance strategies in China. This study used the Community Multiscale Air Quality (CMAQ) and Long-range Energy Alternatives Planning (LEAP) models, with a typical industrial city in the Sichuan Basin as the case study. Five emission reduction scenarios, one integration scenario, and one baseline scenario were set to quantitatively analyze the synergistic effect between carbon emissions and atmospheric pollutant emissions. The results indicate a high synergy between sulfur dioxide and greenhouse gases. For every one-point decrease in the Air Quality Composite Index (AQCI), the Industrial Restructuring Scenario (IR), Other Source Management Scenario (OSM), Transportation Energy Efficiency Improvement Scenario (TEEI), Industrial Energy Efficiency Improvement Scenario (IEEI), and Transportation Restructuring (TR) scenarios would require a reduction in carbon emissions by 56,492.79 kilotons, 39,850.45 kilotons, 34,027.5 kilotons, 22,356.58 kilotons, and 3243.33 kilotons, respectively. The results indicate that governance measures, such as improving transportation structure and upgrading industrial technologies, provide stronger support for simultaneous carbon emissions reductions and air quality improvement.