The importance of drying and grinding samples for determining mobile chromium fractions in polluted river sediments

Abstract

A possible impact of sample preparation on the chemical fractionation results is generally underestimated in studies of forms of occurrence of heavy metals in river sediments. Our analysis of the recently published results of sequential extraction of chromium has revealed the effect of sample grinding on the result of determination of mobile chromium fractions in river sediments. This observation has been experimentally verified along with the analysation of potential effect of river sediment drying conditions on chromium distribution pattern. The studies were carried out on river sediments polluted with tannery effluents (Cr, 29.2–233 mg/kg). The determined content of chromium bound to carbonates in powdered samples was 2 to 7 times higher than those in raw river sediment samples. It was shown that the main reason was the different kinetic characteristics of chromium leaching in these sediments. Using the shrinking core model, it was found that diffusion through the “ash layer” was the rate-controlling step during the extraction of the carbonate fraction of chromium. It has been additionally confirmed that common air drying of sediment samples does not affect the results of chemical fractionation of chromium. The results of our studies are also vital for the assessment of environmental risk posed by river sediments polluted with heavy metals. In the case of sediment samples used in this study, powdering changed the risk category (RAC) from low risk to high risk . Hence, in order to achieve a realistic assessment of chromium mobility and environmental risk, it is advisable to use raw samples, despite their poorer homogeneity, and thus, lower precision of chemical fractionation results. Electronic supplementary material The online version of this article (10.1007/s10661-019-7727-2) contains supplementary material, which is available to authorized users.

Benzo(a)Pyrene in PM10 - Air Monitoring Results in Poland

“…These chemical compounds are persistent in the environment, they bioaccumulate and harmful influence on human health. The biggest threat is caused by PAHs inhaled with ambient air [4,5]. Some compounds from the PAH group are carcinogenic and mutagenic [6][7][8][9].…”

“…Air pollution is considered as one of the main factors affecting the population. It can cause negative changes in the respiratory and circulatory systems, even when concentrations do not exceed permissible levels [4,5,[15][16][17]. It should be highlighted that in many European countries PM10 (particulate matter), NO 2 , and O 3 concentrations still exceeded the permissible limits in 2020 [18].…”

Performance of river sediments after flocculation-pressure filter membrane-vacuum preloading

“…The pressure of the environment and society has been increased in the face of river sediments because of the rapid development of industrial production and cities. Many countries around the world have paid more and more attention to treatment of river sediments (Fang et al 2019a, b;Akcay et al 2003;Pejman et al 2015;Teatini et al 2011;Jankowski et al 2017;Liu and Cai 2019;Trojanowska and Świetlik 2019). Treatment methods of river sediments are different depending on the national conditions of different countries.…”