With the continuous expansion of education industry in China, the construction of PPP project in education field draws more and more attention. In view of the complex financing structure of PPP project, numerous participants and large potential risks, this paper puts forward the method of expert review and analytic hierarchy process. The scheme of this paper starts with the structural organization of PPP project, analyzes the development of PPP model in education industry, and establishes a set of strict process for PPP project in education industry to evaluate the importance of risk factors in the project and monitor the management. The results show that the scheme can strictly control the risk coefficient of the project, ensure the interests of the investors, and improve the overall benefit of the project.