The quadrature modeling technique is nowadays widely used for the nonlinear simulation of RF/microwave communication circuits and systems at the behavioral (system) level. It allows one to simulate the circuit/system performance under real‐world conditions and signals (using several thousand sample frequencies) and to predict such parameters as adjacent channel power ratio, spectral regrowth, and error vector magnitude in a computationally efficient way. But it is a narrowband technique and, consequently, cannot predict harmonics of the carrier frequency and even‐order nonlinear products, to account for the circuit/system frequency response and the bias decoupling network effect. Here, we propose a new behavioral‐level simulation technique (instantaneous quadrature technique) that overcomes these drawbacks, and demonstrate its validity through measurements and harmonic balance simulation. The transformation of envelope transfer characteristics into instantaneous ones is also discussed in detail. © 2000 John Wiley & Sons, Inc. Int J RF and Microwave CAE 10: 221–237, 2000.