The influence of electron beam irradiation, plastic deformation, and re‐irradiation on crystallinity degree, mechanical and sclerometric properties of GUR 1050 used for arthroplasty

Abstract

The article describes the influence of an electron beam irradiation (I), plastic deformation (D), and re-irradiation (R) on the properties of ultrahigh molecular weight polyethylene (GUR 1050). It was found that the modification through irradiation entailed a gradual increase in the degree of crystallinity (after irradiation-I). After plastic deformation and re-irradiation (IDR) the degree of crystallinity decreases which had a direct influence on the mechanical properties. The polymer irradiation only (technique I) resulted in an increase in the maximum stress as compared with the material in the initial state. The application of deformation and re-irradiation (technique IDR) allowed increasing the deformation resistance by more than 40%. Moreover, the irradiation with an electron beam resulted in the increase in hardness (H) and Young's modulus (E) proportionally to the applied irradiation dose and in the reduction of total indentation work (W tot ) and its components. After deformation and re-irradiation the polyethylene hardness went down. The application of technique (I) caused an improvement to the material abrasion resistance (reduction of parameter PD-working scratch depth) with the increasing irradiation dose. The introduction of deformation and re-irradiation did not have a material impact on parameter (PD) increasing at the same time elastic properties of UHMWPE (increase in parameter NPS-elastic recovery). Modification IDR has changed the wear mechanism (b) toward ploughing and has increased the abrasionresistance index (W b ) and also significantly reduced the coefficient of friction (l) of GUR 1050. V C 2016 Wiley Periodicals, Inc. J. Appl.Polym. Sci. 2016, 133, 43683.