The influence of hydrogen sulfide on corrosion of iron under different conditions

Ma, Houyi; Cheng, Xiaoliang; Li, Guiqiu; Chen, Shenhao; Quan, Zhenlan; Zhao, Shiyong; Niu, Lin

doi:10.1016/s0010-938x(00)00003-2

Cited by 476 publications

(224 citation statements)

References 20 publications

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“…These observations were also supported by Videm et al [90] and Ma et al [92] who recorded very rapid reductions in anodic dissolution at low H2S concentrations.…”

Section: Co2-h2o-h2s Environmentssupporting

confidence: 79%

Internal corrosion of carbon steel pipelines for dense-phase CO₂transport in carbon capture and storage (CCS) – a review

Barker

Hua

Neville

2016

International Materials Reviews

134

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Carbon Capture and Storage (CCS) has been highlighted as a potential method to enable the continued use of fossil-fuelled power stations through the abatement of carbon dioxide (CO2). A complete CCS cycle requires safe, reliable and cost effective solutions for the transmission of CO2 from the capturing facility to the location of permanent storage. In subsequent sections, early laboratory and field corrosion experience relating to natural dense phase CO2 transport for the purposes of enhanced oil recovery (EOR) are summarised along with more recent research efforts which focus on identifying the role of anthropogenic impurities in the degradation processes. For each system impurity, the reaction rates, mechanisms and corrosion product composition/morphology expected at the steel surfaces are discussed, as well as each component's ability to influence the critical water content required to initiate corrosion. Potential bulk phase reactions between multiple impurities are also evaluated in an attempt to help understand how the impurity content may evolve along a long distance pipeline.The likelihood of stress-corrosion cracking and hydrogen-induced cracking is discussed and the various corrosion mitigation techniques which exist to control degradation to acceptable 2 levels are reviewed. Based on the current research performed in the context of impure dense phase CO2 corrosion, issues associated with performing laboratory experiments to replicate field conditions and the challenges such limitations present in terms of defining the safe operating window for CO2 transport are considered.

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“…These observations were also supported by Videm et al [90] and Ma et al [92] who recorded very rapid reductions in anodic dissolution at low H2S concentrations.…”

Section: Co2-h2o-h2s Environmentssupporting

confidence: 79%

Internal corrosion of carbon steel pipelines for dense-phase CO₂transport in carbon capture and storage (CCS) – a review

Barker

Hua

Neville

2016

International Materials Reviews

134

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“…However, under certain special operating conditions with low H 2 S concentrations (<0.04 mmol/l, <15 ppm or <0.05 psi), pH values of 3-5 and immersion times exceeding two hours, the corrosion process can be inhibited, which significantly decreases the corrosion rate [1][2][3][4][5][6][7][8][9] , as shown in the results obtained for solution 1 in this study.…”

Section: Resultsmentioning

confidence: 51%

“…In aqueous environments, hydrogen sulphide dissociates and produces different chemical species with different concentrations depending on the pH, temperature and H 2 S concentration. For each pH value, the predominant chemical species determines the oxidation and reduction reactions and characterizes the corrosive process [1][2][3] . According to Kane 27 , for most steels in H 2 S-containing environments, the corrosion rates tend to increase with decreasing pH of the aqueous solution.…”

Section: Resultsmentioning

confidence: 99%

“…Below this pH, the solubility of these sulphides is sufficiently high for the corrosion rates to also be high. Above pH = 7, a passivating film of mackinawite is developed [1][2][3] . At pH values of 3-5, an inhibitive effect of H 2 S is observed, as a protective ferrous sulphide film (FeS) forms on the electrode surface 3,9 .…”

Section: Resultsmentioning

confidence: 99%

“…It is well known that H 2 S originating from different processes in the oil and gas industry can accelerate the anodic and cathodic reactions of the corrosion process: iron dissolution and hydrogen evolution reaction, respectively [1][2][3][4][5][6][7][8][9][10] . Studies focusing on improving the resistance of pipeline steels to H 2 S corrosion to avoid failures during oil and gas transport have been reported [9][10][11][12][13][14] .…”

Section: Introductionmentioning

confidence: 99%

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Corrosion Evaluation of SAW Welded API 5L X-80 Joints in H2S-Containing Solution

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Highly Selective Fluorescence Detection of Hydrogen Sulfide by Using an Anthracene‐Functionalized Cyclam–Cu^II Complex

et al. 2013

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An anthracene-functionalised cyclam-copper(II) complex for the detection of HSin aqueous environments has been prepared. This probe displays poor fluorescence but can selectively and sensitively detect HSanions in water over other anions, biothiols and common oxidants such as H 2 O 2 through remarkably enhanced emission. This turn-on response in the presence of the HSanion is ascribed to a demetallation reac-[a] Centro de Reconocimiento Molecular y Desarrollo Tecnológico Supporting Information (see footnote on the first page of this article): General techniques, synthesis and characterisation of 1 and [Cu(1)] 2+ ; sensing features of [Cu(1)] 2+ ; cell viability assay of [Cu(1)] 2+ and fluorescence microscopy studies.

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The influence of hydrogen sulfide on corrosion of iron under different conditions

Cited by 476 publications

References 20 publications

Internal corrosion of carbon steel pipelines for dense-phase CO₂transport in carbon capture and storage (CCS) – a review

Internal corrosion of carbon steel pipelines for dense-phase CO₂transport in carbon capture and storage (CCS) – a review

Corrosion Evaluation of SAW Welded API 5L X-80 Joints in H2S-Containing Solution

Highly Selective Fluorescence Detection of Hydrogen Sulfide by Using an Anthracene‐Functionalized Cyclam–Cu^II Complex

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The influence of hydrogen sulfide on corrosion of iron under different conditions

Cited by 476 publications

References 20 publications

Internal corrosion of carbon steel pipelines for dense-phase CO2transport in carbon capture and storage (CCS) – a review

Internal corrosion of carbon steel pipelines for dense-phase CO2transport in carbon capture and storage (CCS) – a review

Corrosion Evaluation of SAW Welded API 5L X-80 Joints in H2S-Containing Solution

Highly Selective Fluorescence Detection of Hydrogen Sulfide by Using an Anthracene‐Functionalized Cyclam–CuII Complex

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Product

Resources

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Internal corrosion of carbon steel pipelines for dense-phase CO₂transport in carbon capture and storage (CCS) – a review

Internal corrosion of carbon steel pipelines for dense-phase CO₂transport in carbon capture and storage (CCS) – a review

Highly Selective Fluorescence Detection of Hydrogen Sulfide by Using an Anthracene‐Functionalized Cyclam–Cu^II Complex