The influence of medium polarity on the kinetics and mechanism of interaction of aliphatic nitroxides with hydroperoxyl radicals

Плисс, Е. М.; Soloviev, Mikhail; Sen, V. D.; Pliss, R. E.; Сирик, А. В.; Тихонов, И. В.

doi:10.1007/s11144-021-01948-3

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Cited by 3 publications

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“…The value 2k 3 = (5.4±0.2)•10 6 L mol -1 s -1 was used to determine the k 4 value. 13 The data obtained are given in Table 1. When calculating k 4 , f was accepted to be two, since this value corresponds to one cycle of transformation via reactions (4.1) and (4.2).…”

Section: Resultsmentioning

confidence: 99%

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Catalytic inhibition of olefin oxidation with Mn and Cu compounds

et al. 2021

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The rate constants and kinetic coeffi cients of inhibition (f kin ) for olefi ns oxidized with the transition metal compounds (M n ) were measured by highly sensitive microvolumometry at 323 K in combination with kinetic modeling. The cyclic mechanism of the reactions of hydr oxyl radicals with M n leading to the multiple chain termination was confi rmed as indicated by the observed eff ect of long-term inhibition of the oxidation of the substrates with M n and obtained values of f kin > 10 2 .

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Section: Resultsmentioning

confidence: 99%

“…When calculating k 4 , f was accepted to be two, since this value corresponds to one cycle of transformation via reactions (4.1) and (4.2). 13 The kinetic coeffi cient of inhibition (f kin ) was calculated taking into account the experimental kinetic curves of oxygen uptake. For example, it follows from the data in Fig.…”

Section: Resultsmentioning

confidence: 99%