The influence of multilayer structure on mechanical behavior of TiN/TiAlSiN multilayer coating

Ma, Huijun; Miao, Qiang; Zhang, Gaohui; Liang, Wenping; Wang, Yan; Sun, Ziwang; Hua, Lin

doi:10.1016/j.ceramint.2021.01.117

Cited by 39 publications

(9 citation statements)

References 33 publications

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“…For example, Ye et al [113] used the indentation approach to analyze the toughness of homogeneous and layered design coatings and employed FIB technology to examine the indentation morphology. Ma et al [117] also employed a multi-arc ion plating process to develop a Ti-Al-Si-N coating with a homogeneous structure and a Ti-N / Ti-Al-Si-N layered design on titanium alloy. When compared to the Ti-Al-Si-N homogeneous structure cladding, the Ti-N / Ti-Al-Si-N layered design coating greatly improves resistance to wear, bonding strength, and hardness of the coating.…”

Section: Layered Design Claddingmentioning

confidence: 99%

Improving the Resistance to Wear and Mechanical Characteristics of Cladding Layers on Titanium and its Alloys: A Review

Ranjan¹,

Das²

2023

Tribol. Ind.

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Because of inadequate hardness, low resistance to wear, and excess friction coefficient of titanium, and its alloys are limited in their applicability. Cladding, a type of surface modification process, is used to create layers on titanium and its alloys that have superior mechanical qualities, wear characteristics, oxidation resistance at high temperatures, and good biocompatibility. Material selection is critical for achieving the increased qualities mentioned above, in addition to various cladding techniques and associated process parameters. A review of the outcomes of various common wear-resistant cladding techniques applied to the titanium alloy surface is the subject of this study. The most important functional claddings in this domain are also presented and investigated in depth. The present issues and future initiatives are also discussed, with an emphasis on identifying knowledge and technological gaps as well as attempting to establish future research possibilities. On this foundation, it is suggested that in the coming years, resistant-to-wear cladding with significant improvements in toughness and hardness should progress on the path of smart manufacturing techniques, optimising and precisely customising microstructural configurations, and developing numerical simulation techniques of cladding.

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Section: Layered Design Claddingmentioning

confidence: 99%

Improving the Resistance to Wear and Mechanical Characteristics of Cladding Layers on Titanium and its Alloys: A Review

Ranjan¹,

Das²

2023

Tribol. Ind.

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“…Such as the TiAlN/MeN (Me = Zr, Ti, and Cr − ) multilayers, whose mechanical and thermal properties can enhance the lifespan of cutting tools. Particularly, multilayer architecture with coherent interfaces releases excessive stress during the growth of TiAlSiN coatings and improves their weak adhesion to the substrate, which prevents the coating from spalling . Therefore, combined with the excellent properties of TiAlSiN coating and the above-mentioned advantage of coherent interfaces, the construction of the TiAlSiN/TiAlN structure may become an effective way in severe applications.…”

Section: Introductionmentioning

confidence: 99%

“…Particularly, multilayer architecture with coherent interfaces releases excessive stress during the growth of TiAlSiN coatings and improves their weak adhesion to the substrate, which prevents the coating from spalling. 26 Therefore, combined with the excellent properties of TiAlSiN coating and the above-mentioned advantage of coherent interfaces, the construction of the TiAlSiN/TiAlN structure may become an effective way in severe applications. Pei et al 27 have demonstrated that epitaxial growth of TiAlSiN/TiAlN multilayer leads to superior thermal and mechanical properties as compared to monolithic coatings.…”

Section: Introductionmentioning

confidence: 99%

Investigation on the Interface Structure, Mechanical Properties, and Thermal Stability of TiAlSiN/TiAlN Multilayers

Du,

Zhang,

Chen

et al. 2023

ACS Appl. Mater. Interfaces

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Recently, the TiAlSiN/TiAlN coatings with excellent mechanical and thermal properties have great potential for protective applications that face deteriorated service environments. Here, we systematically investigate the interface structure, mechanical properties, and thermal stability of TiAlSiN/TiAlN multilayers with varied Al and Si contents of TiAlSiN sublayer. B o t h T i 0 . 5 3 A l 0 . 3 8 S i 0 . 0 9 N / T i 0 . 5 2 A l 0 . 4 8 N ( M L _ 1 ) a n d Ti 0.48 Al 0.38 Si 0.14 N/Ti 0.52 Al 0.48 N (ML_2) exhibit the face-centered cubic structure through epitaxial growth, whereas the Ti 0.43 Al 0.48 Si 0.09 N/Ti 0.52 Al 0.48 N (ML_3) shows a mixed cubic/ wurtzite (c/w) structure. This mechanism is explored by first-principles calculations that the increased content of Al and Si within the TiAlSiN sublayer is detrimental to the formation of a coherent interface. Meanwhile, the change of interfacial structure leads to a variation in hardness from ∼35.6 GPa of ML_1 to ∼35.4 GPa of ML_2 and then to ∼30.9 GPa of ML_3. In addition, ML_1 presents a delayed thermal decomposition by ∼100 °C, compared to those of ML_2 and ML_3 multilayers.

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“…So, TiAlN and TiSiN coatings are limited to industrial applications with a high degree of thermal exposure [7,15]. The addition of a fourth element to the coating and the application of multilayer coatings are two of the solutions that have been proposed to solve this problem [15,[21][22][23][24]. On the one hand, different studies have proved that TiAlSiN coatings provide better properties in terms of hardness, oxidation resistance, and thermal stability than TiAlN coatings [22,25].…”

Section: Introductionmentioning

confidence: 99%

Improved Adhesion and Tribological Properties of AlTiN-TiSiN Coatings Deposited by DCMS and HiPIMS on Nitrided Tool Steels

et al. 2021

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Hard coatings, such as AlTiN-TiSiN, deposited by Physical Vapor Deposition (PVD) techniques are widely used in industrial applications to protect and increase the lifetime of industrial components, such as cutting tools, dies, and forming tools. Despite their great properties, such as high hardness and wear and oxidation resistance, they are limited in cases of severe conditions due to the poor adhesion between the coating and the substrate. Duplex treatments have commonly been used to improve the adhesive properties of PVD coatings, especially those of the cathodic arc evaporation type. The purpose of this study is to achieve coatings with the good properties of the Magnetron Sputtering processes but with higher adhesion than that achieved with these techniques, thus achieving coatings that can be used under the most severe conditions. In this work, an AlTiN-TiSiN coating was deposited by a combination of DC Magnetron Sputtering (DCMS) and High-Power Impulse Magnetron Sputtering (HiPIMS) after a gas nitriding pretreatment on 1.2379 and Vanadis 4 tool steels. Mechanical (ultra-microhardness and scratch tests) and tribological tests were carried out to study the improvement in the properties of the coating. Duplex-treated samples showed improved adhesion between the coating and the substrate, with second critical load (Lc2) values greater than 100 N. Furthermore, they showed great toughness and wear resistance. These results show that this type of coating technique could be used in the most extreme applications and that they can compete with other techniques and coatings that to date they have not been able to compete with.

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The influence of multilayer structure on mechanical behavior of TiN/TiAlSiN multilayer coating

Cited by 39 publications

References 33 publications

Improving the Resistance to Wear and Mechanical Characteristics of Cladding Layers on Titanium and its Alloys: A Review

Improving the Resistance to Wear and Mechanical Characteristics of Cladding Layers on Titanium and its Alloys: A Review

Investigation on the Interface Structure, Mechanical Properties, and Thermal Stability of TiAlSiN/TiAlN Multilayers

Improved Adhesion and Tribological Properties of AlTiN-TiSiN Coatings Deposited by DCMS and HiPIMS on Nitrided Tool Steels

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