The quality of English teaching cannot be separated from the students’s accumulation and mastery of vocabulary, and sufficient vocabulary can ensure that students feel easy and comfortable in the language application. However, there are still some problems in teaching English vocabulary in colleges and universities, such as single presentation method, lack of real context, and other difficulties. With the rapid development of mobile Internet, the share of smart mobile devices among college students has increased, which in turn has laid the foundation for the development of new learning modes. The mobile terminal-mediated learning mode in English classroom teaching has become a hot topic of research nowadays, of which English vocabulary teaching has become a typical example. This paper is designed as a system model of edge computing, in which the user terminal device can connect wirelessly with each MECS and offload the tasks to be processed on the MECS, which helps the user terminal device to process and return the results to the user terminal device. The research in this paper also provides a basis for students’ independent and lifelong learning of English words and for schools’ information technology to serve English vocabulary teaching and learning.