The Influence of Solvent on the Solvolysis of Ethyl Cinnamate in Water Acetone Mixed Solvent System

Abstract

Abstract-

Kinetics and Solvent Effect on Hydrolysis of Ethyl Cinnamate in Water-Methanol Mixture

“…Finally, it is inferred that with rise of temperature, the number of water molecule associated with activated complex increases as the proportion of bulky form of water molecule increase with increase in MEOH content in the water-ethanol mixture and it explain that when MEOH is added to water, the mechanistic path of reaction is changed from biomolecular to unimolecular in similar way as observed by parker and Tomilinson [11] and recently by Singh A K [12] …”

“…Such decrease in rate constant with increasing proportion of organic co-solvent like methanol have also reported by Elsemongy [5], and recently by Singh A K [6]. …”

Studies of Solvent Effect of Aquo-Methanol Solvent System on Kinetics and Activation Parameters of Base Catalised Hydrolysis of Ethyl Cinnamate

“…From Table 1 it is observed that the values of specific rate constant is decrease with increase of temperature which is quite in agreement with theory of Hughes and Ingold [4] and Singh et al [5].…”

Studies of Solvent Effect of Aquo-Methanol Solvent System on Kinetics and Activation Parameters of Base Catalised Hydrolysis of Ethyl Cinnamate

“…From Tab-1 it is observed that the values of specific rate constant is decrease with increase of temperature which is quite in agreement with theory of Hughes and Ingold [4] and Singh A K [5] …”