Abstract. The Nickel-Titanium (Ni-Ti) alloys are the most attractive amongst shape memory alloys (SMA) due to their good functionality properties coupled with high strength and good ductility. The transformation temperatures in Ti-rich NiTi SMA can be altered with suitable thermal and/or mechanical treatments to obtain martensitic Ti-Rich Ni-Ti SMA (Ni-51at%Ti) that will contribute to different phase transformation sequences (one, two and 300 minutes in vacuum), (ii) followed by multiple steps of marforming (30% thickness reduction by cold rolling), (iii) four distinct final thermal treatments (400, -Ray Diffraction (XRD) at room (ER) and X-Ray Diffraction (XRD) were used to identify the transformation temperatures and the phases that are present after all steps of thermomechanical treatments.