The influence of the carbon double bond on the structure and photophysical properties of copper(I) coordination polymers

Characterization and Catalytic Activity of New Metal‐organic Frameworks Resulted from Self‐assembly of Ph3SnCl, K[Cu(CN)2] and Nitrogen Donor Ligands

“…[8][9][10][11][12] The copper cyanide system is particularly attractive from the viewpoint of structural engineering because of the previously reported versatility of {CuCN} n structural motifs in accommodating various ligand-imposed geometric requirements. [13][14][15][16][17] On the other hand, organometallic R 3 Sn ＋ (R＝Me or Ph) unit can act as a connecting moiety by axial anchoring to two donor atoms, exhibiting trigonal bipyramidal configuration, creating structures of high dimensionality. [18][19][20][21][22][23][24][25][26][27] It has been shown that organometallic R 3 E ＋ units (R＝Me, Et, n-propyl, n-butyl, phenyl; E＝Sn, Pb) can bridge the cyanometallate anions, M(CN) n q-, in much the same fashion as silver do in SPB 28 except that the greater complexity of the R 3 E ＋ units leads to complicated three-dimensional polymer.…”