The Insights of Lithium Metal Plating/Stripping in Porous Hosts: Progress and Perspectives

Abstract

Lithium (Li) metal is strongly regarded as a promising anode for next‐generation secondary batteries. However, the nonuniform plating/stripping and volume fluctuation of the Li metal anode give rise to low Coulombic efficiency and short lifespan of Li metal batteries, which hinder practical applications of the Li metal anode. A composite Li metal anode that employs a stable porous host has been proposed as a promising strategy to regulate the behaviors of Li plating/stripping and relieve volume fluctuation. In a porous host, the basic building block is a pore. The pore structure affects the distribution of electric and Li‐ion concentration fields during Li plating/stripping, thus regulating Li plating/stripping and the lifespan of the composite Li metal anode. Therefore, herein, the recent progress in investigating the behavior of Li plating/stripping in a pore based on liquid electrolytes is summarized from the aspects of pore diameter, depth, and tortuosity. Furthermore, the perspectives of rational design of the pore structure for a composite Li metal anode are presented to promote the development of Li metal anodes.

The Growth Mechanism of Lithium Dendrites and its Coupling to Mechanical Stress

“…porous metals or carbons) minimize dendritic growth. [41][42][43] A usual interpretation of this effect is the smaller current density at such substrates, which has been suggested to avoid electrolyte depletion. Since our previous results indicate that depletion is not dominating the growth, [15] we suggest an alternative explanation of the effect: The larger substrate area results in a large substrate-lithium interface, which might provide large number of insertion sites.…”

Status and Prospects of MXene‐Based Lithium–Sulfur Batteries

“…To overcome the dendrite problem in Li anode, designing a host for Li metal is an efficient strategy. [155] MXene materials are considered as a potential Li host to suppress the formation and growth of Li dendrites for realizing stable Li anode. The terminations on MXenes have good affinity to Li to guide its nucleation.…”

The growth mechanism of lithium dendrites and its coupling to mechanical stress

“…porous metals or carbons) minimize dendritic growth. [50][51][52] A usual interpretation of this effect is the smaller current density at such substrates, which has been suggested to avoid electrolyte depletion. Since our previous results indicate that depletion is not dominating the growth, 15 we suggest an alternative explanation of the effect: the larger substrate area results in a large substrate-lithium interface, which might provide large number of insertion sites.…”