The insights of pet cokes/palm kernel shell activated carbon as CO₂ adsorbent: equilibrium, kinetics, thermodynamics, and regeneration performance

Abstract

BACKGROUND: Over the years, activated carbon has been widely used for environmental applications, including liquid or gas phase applications. However, there are many hurdles for researchers in the activated carbon field to overcome when it comes to non-renewable materials, the utilization of individual precursors, and the complex multistep procedures of activated carbon synthesis. Therefore, in this study, the facile mechanochemical potassium carbonate (K 2 CO 3 ) activation of blended precursors palm kernel shell and petroleum cokewas investigated in terms of the activated carbon yield and carbon dioxide (CO 2 ) adsorption capacity. RESULTS:The optimum configuration of the activated carbon production was found at temperature of 680°C, holding time of 60 min, and impregnation ratio of 1.75:1. The CO 2 adsorption data at 25-120°C was best represented by the Sips model with R 2 > 0.9999, where maximum CO 2 adsorption capacity (q max ) was within the range of 2.24-4.32 mmol/g. The kinetic analysis was well-represented by the pseudo-second order model due to the high R 2 and low sum of square of errors (ERRSQ) value. In terms of thermodynamic analysis, it showed that the CO 2 adsorption process was physical, exothermic, and spontaneous at lower temperature. CONCLUSION: Overall, the integration of agricultural and industrial waste to value-added activated carbon was feasible not only in reducing waste disposal problems but also in facilitating CO 2 mitigation.

In Focus: Application of resilient environmental technologies for waste utilization and resource recovery

“…Thus, any attempt to capture carbon should be encouraged. The first article by Rashidi & Yusup 1 investigates the equilibrium, kinetics, thermodynamics, and regeneration performance of pet cokes/palm kernel shell activated carbon as CO 2 adsorbent. The temperature, holding time and impregnation ratio to obtain the optimum configuration of activated carbon production were found in the study.…”