The size, distribution, and volume fraction of second phases are altered during extrusion deformation. As a result, the microgalvanic corrosion of Mg alloys will change. The corrosion behaviors of cast and extruded EW75 (Mg-5Y-7Gd-1Nd-0.5Zr) were studied by scanning electron microscopy observations, hydrogen evolution and weight loss measurements, and electrochemical tests. Extruded EW75, which has a lower volume fraction, smaller size, and more uniform distribution of second phases, is found to exhibit better corrosion resistance than cast EW75; the difference can be attributed to weaker microgalvanic corrosion and a more protective surface film. Magnesium and its alloys have become increasingly attractive in the automotive and aerospace industries because of their many advantages, such as low density and high specific strength and stiffness. [1][2][3] In recent years, rare earth (RE) Mg alloys have received considerable attention.4-9 Mg-RE alloys, especially the Mg-Gd-Y system, exhibit high strength and good creep resistance at both room temperature and elevated temperatures. [10][11][12][13] To improve the mechanical properties of Mg-RE alloys, altering the microstructure by deformation treatment is known to be a suitable and efficient method.14 However, the changes in the microstructures may strongly affect the corrosion resistance of the alloy. [15][16][17] The volume fraction, size, and distribution of second phases are altered during the deformation process.18-20 Hence, the microgalvanic corrosion between the second phases and the Mg matrix in the received cast and extruded (or forged) alloys should be different.Microgalvanic corrosion between the second phases and the Mg matrix is one of the most significant types of corrosion in Mg alloys. [21][22][23] In our previous work, we found that microgalvanic corrosion of cast EW75 differs from that of other Mg alloy systems. 24 The second phases in cast EW75 consisting of Mg and REs are more active than the Mg matrix, and they preferentially dissolve in microgalvanic corrosion. Moreover, REs that are bound in the second phases contribute to the construction of the initial surface film. A surface film containing REs is reportedly more protective. [25][26][27] Moreover, it was found that grain size influences the corrosion resistance little, which can be attributed to the good electrochemical uniformity of grain boundaries in comparison with the existence of second phases. The above analysis suggests that the microgalvanic corrosion between the second phases and the Mg matrix is very important to the corrosion mechanism and corrosion resistance of Mg-RE alloys. Therefore, if this type of corrosion were changed by the deformation process, the corrosion mechanism and corrosion resistance of Mg-RE alloys would differ greatly.The aim of this work is to investigate the corrosion behaviors of cast and extruded EW75 Mg alloys and clarify the effect of extrusion deformation on the corrosion resistance.
ExperimentalCast and extruded EW75 (Gd: 7.04 wt%, Y: 4.53 wt%, Nd: 1...