Hydrate formation is a major flow assurance issue in the petroleum
industry, and the knowledge of hydrate inhibitor distribution is essential
for the economic gas transportation and processing operation. A number
of measurements were made to determine the solubility of methane,
the main constituent in natural gas, in methanol and ethanol aqueous
solutions. The results showed that the addition of water significantly
reduces the solubility in methanol and ethanol. Methanol and ethanol
are two of the most commonly used gas hydrate inhibitors in the petroleum
industry. The solubility data are important in developing binary interaction
parameters used in predicting inhibitor distribution in multicomponent
systems containing water. To fill the significant gap in the open
literature data, the solubility of methane in 70 and 50 wt % methanol
and ethanol solutions at 273.15–298.15 K and 0.46–44
MPa were measured. The average repeatability of the experimental results
was calculated to be 2.5%. The results from this work and literature
were used to optimize the interaction parameters of the CPA-SRK72
equation of state. The model calculations using a single variable
binary interaction parameter was able to reproduce the new experimental
results with a significant increase in accuracy.