The Isothermal Section of the Sn-Sb-Ni Ternary System at 270°C

Chen, Yueting; Fang, Gu; Chen, Chih-Chi

doi:10.1007/s11664-014-3223-1

Cited by 2 publications

(1 citation statement)

References 26 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Recently, two theoretical assessments of the Ni-Sn system performed by use of the CALPHAD approach were published, one by Zemanova et al, 14 which modeled the Ni 3 Sn 2 phase as one phase, the other by Liu et al, 15 that includes the Ni 3 Sn 2 -LT modification. To construct a thermodynamic database for Pb-free soldering, several Sn-Ni-based ternary systems have been investigated, for example, Sn-Ni-Cu, 16 Sn-Sb-Ni, 17,18 Sn-Ni-Ag, 19 Sn-Ni-Bi, 20,21 Sn-Ni-Zn, 22 and Sn-NiAu. 23,24 The Sn-V system has also been investigated experimentally [25][26][27] and assessed thermodynamically 28,29 by several research groups.…”

Section: Literature Surveymentioning

confidence: 99%

Phase Equilibria of the Sn–Ni–V System: The 980°C Isothermal Section and the Sn-Rich Corner at 600°C and 300°C

Peng

et al. 2015

Journal of Elec Materi

View full text Add to dashboard Cite

Ternary Sn-Ni-V alloys were prepared and annealed at 980°C, 600°C, and 300°C for 15, 60 and 60 days, respectively. The annealed alloys were metallographically examined and the equilibrium phases formed were identified on the basis of determination of composition and x-ray diffraction analysis. The isothermal region of the ternary Sn-Ni-V system at 980°C was studied. Nine three-phase regions and more than 20 conjugate lines were detected at 980°C. The range of composition of VNi 2 Sn at 980°C spans 24.5-59.2 at.% V, 52.1-25.5 at.% Ni, and 15.3-23.4 at.% Sn. Its lattice constant increases with increasing V content. A sharp increase near 40.4 at.% V is indicative of a second-order transition. It is believed that atomic site occupation changed when the V content was >40.4 at.%. The maximum solubility of V in Ni 3 Sn 2 can reach 23.3 at.%; that in Ni 3 Sn is below 0.6 at.%. Up to 3.4 at.% Ni dissolves in V 3 Sn. The Sn-rich corner of the Sn-Ni-V system at 600°C and 300°C was also investigated experimentally. The solubility of Ni in VSn 2 and V in Ni 3 Sn 4 at 600°C and 300°C are both less than 0.5 at.%.

show abstract